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القسم قسم الكيمياء
المرحلة 3
أستاذ المادة محمد هاشم مطلوب الغرابي
26/12/2017 20:35:00
Close-packed structure: When the atoms of a monatomic solid are imagined to be relatively incompressible spheres, they might be very tightly packed together in the most compact arrangement for spheres. [Note: This is expected since the cohesive energy for metallic and Van der Waals bonding increases with the number of nearest neighbors, up to the point where core overlap becomes significant]. Two stacking sequences for close-packed structures are considered: 1) Face-centered cubic (fcc) structure. 2) Hexagonal close-packed (hcp) structure. In general, the arrangement of spheres in such structures implies the followings: a) Each sphere has six touching neighbors in a close-packed plane array of spheres, as shown in figure 19. Such plane arrays with hexagonal symmetry can be stacked together to make the most compact monoatomic solid in two simple ways. b) Each atom has twelve nearest neighbors; these 12 neighbors are distributed as follows: six in the plane as in figure 19, three in the plane above and three in the plane below, as shown in figure 23. Close-packed fcc structure: When the spheres with radius r for one type of atoms are considered, for a two-dimensional packing, a hexagonal lattice with primitive cell edge, a=2r, is formed. The stacking of layers is as follows: a) The first layer A of spheres is formed in a plane of arrays of hexagonal lattice in 2-D, as mentioned above. b) The second layer B of spheres is located such that sphere centers are over the points labeled (+) (i.e. center of sphere B is on a point at the center (hole) of the well formed by three spheres of A (below)). c) The third layer C of spheres is placed on top of B and is displaced so that its atoms fall on top of the spaces in layer B which were also spaces in layer A (labeled o).
المادة المعروضة اعلاه هي مدخل الى المحاضرة المرفوعة بواسطة استاذ(ة) المادة . وقد تبدو لك غير متكاملة . حيث يضع استاذ المادة في بعض الاحيان فقط الجزء الاول من المحاضرة من اجل الاطلاع على ما ستقوم بتحميله لاحقا . في نظام التعليم الالكتروني نوفر هذه الخدمة لكي نبقيك على اطلاع حول محتوى الملف الذي ستقوم بتحميله .
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